(from mathisfun.com)
The answer isn't too complicated. The equation for finding the measure of an interior angle of a regular n-gon is 360/n. So the measure of an interior angle of a triangle is 60, and that of a square is 90, and that of a hexagon is 120. In a tessellation, the corners of the shape being tessellated must meet. And the golden reason for a regular tessellation is having those corners all add up to 360. When triangles tessellate, six corners meet. 6 corners x 60 degrees= 360 degrees. With a square, it's 4 x 90...which is also 360. And with a hexagon, it's 3 x 120 (yes- 360!). I knew that triangles tessellated (and it was pretty easy to figure out that squares tessellate too). If you remember that six regular triangles make up a hexagon (as you can see in the tessellating triangles picture) it's easy to realize that a hexagon would also tessellate. So to figure out if a regular n-gon would tessellate, you would use the equation:
360/n x number of corners meeting in tessellation
If this again equals 360, then the regular n-gon tessellates. But let me remind you right now--unless its a triangle, square or hexagon, that equation won't work